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| US Open | ||
| Surface: Hard | Date: Aug. 30 - Sep. 12 | Seed: 16 |
| Round | Opponent | W / L | Result |
| First Round | Dayana Yastremska | Win | 3-6, 6-4, 7-6 (7-3) |
| Second Round | Anhelina Kalinina | Win | 6-3, 6-2 |
| Third Round | Sloane Stephens | Win | 5-7, 6-2, 6-3 |
| Fourth Round | Leylah Fernandez | Loss | 6-4, 6-7 (5-7), 2-6 |
| Western & Southern Open | ||
| Surface: Hard | Date: Aug. 15 - Aug. 22 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Maria Sakkari | Win | 6-2, 6-2 |
| Second Round | Elina Svitolina | Win | 7-5, 2-6, 6-4 |
| Third Round | Jelena Ostapenko | Win | 4-6, 6-2, 7-5 |
| Quarterfinals | Petra Kvitova | Win | 6-4, 3-3 Retired |
| Semifinals | Ashleigh Barty | Loss | 2-6, 5-7 |
| Wimbledon | ||
| Surface: Grass | Date: Jun. 28 - Jul. 11 | Seed: 25 |
| Round | Opponent | W / L | Result |
| First Round | Nina Stojanovic | Win | 6-4, 6-3 |
| Second Round | Sara Sorribes Tormo | Win | 7-5, 5-7, 6-4 |
| Third Round | Aliaksandra Sasnovich | Win | 2-6, 6-0, 6-1 |
| Fourth Round | Cori Gauff | Win | 6-4, 6-4 |
| Quarterfinals | Karolina Muchova | Win | 6-2, 6-3 |
| Semifinals | Ashleigh Barty | Loss | 3-6, 6-7 (3-7) |
| Bad Homburg Open | ||
| Surface: Grass | Date: Jun. 20 - Jun. 26 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Ekaterina Yashina | Win | 6-1, 6-1 |
| Second Round | Anna Blinkova | Win | 6-0, 6-2 |
| Quarterfinals | Amanda Anisimova | Win | 2-6, 6-3, 6-3 |
| Semifinals | Petra Kvitova | Win | 3-6, 6-4, 7-6 (7-3) |
| Final | Katerina Siniakova | Win | 6-3, 6-2 |
| bett1open | ||
| Surface: Grass | Date: Jun. 14 - Jun. 20 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Misaki Doi | Win | 6-2, 6-1 |
| Second Round | Victoria Azarenka | Loss | 3-6, 5-7 |
| Roland Garros | ||
| Surface: Red Clay | Date: May 30 - Jun. 13 | Seed: 26 |
| Round | Opponent | W / L | Result |
| First Round | Anhelina Kalinina | Loss | 2-6, 4-6 |
| Internazionali BNL d'Italia | ||
| Surface: Red Clay | Date: May 9 - May 16 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Alize Cornet | Win | 6-2, 7-5 |
| Second Round | Simona Halep | Win | 1-6, 3-3 Retired |
| Third Round | Jelena Ostapenko | Loss | 6-4, 3-6, 4-6 |
| Mutua Madrid Open | ||
| Surface: Hard | Date: Apr. 29 - May 9 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Marketa Vondrousova | Win | 7-6 (7-5), 6-1 |
| Second Round | Petra Kvitova | Loss | 4-6, 5-7 |
| Porsche Tennis Grand Prix | ||
| Surface: Clay | Date: Apr. 19 - Apr. 25 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Ekaterine Gorgodze | Win | 6-2, 6-2 |
| Second Round | Elina Svitolina | Loss | 6-7 (4-7), 3-6 |
| Miami Open presented by Itau | ||
| Surface: Hard | Date: Mar. 23 - Apr. 4 | Seed: 24 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Renata Zarazua | Win | 6-0, 6-0 |
| Third Round | Victoria Azarenka | Loss | 5-7, 2-6 |
| Dubai Duty Free Tennis Championships | ||
| Surface: Hard | Date: Mar. 7 - Mar. 13 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Caroline Garcia | Loss | 6-3, 2-6, 4-6 |
| Qatar Total Open 2021 | ||
| Surface: Hard | Date: Mar. 1 - Mar. 6 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Cagla Buyukakcay | Win | 6-4, 6-2 |
| Second Round | Anett Kontaveit | Loss | 1-6, 4-6 |
| Australian Open | ||
| Surface: Hard | Date: Feb. 8 - Feb. 21 | Seed: 23 |
| Round | Opponent | W / L | Result |
| First Round | Bernarda Pera | Loss | 0-6, 4-6 |
| Grampians Trophy | ||
| Surface: Hard | Date: Feb. 3 - Feb. 7 | Seed: 8 |
| Round | Opponent | W / L | Result |
| First Round | Katerina Siniakova | Win | 6-3, 4-6, 6-3 |
| Second Round | Ons Jabeur | Win | 6-4, 6-4 |
| Quarterfinals | Maria Sakkari | Loss | 4-6, 2-6 |
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